Search results for "Dual fluorescence"

showing 3 items of 3 documents

Substituent-induced coupling of the two lowest excited singlet states of 2-methoxy-derivatives of 4-(N,N-dimethylamino)- and 4-(N-methylamino)benzoni…

2002

The title compounds both exhibit strong features of interaction of their two lowest excited states, but only one of them, the dimethylamino derivative, exhibits dual fluorescence. This is a direct indication that state interaction and dual fluorescence are not directly related.

Dual fluorescenceCoupling (electronics)chemistry.chemical_compoundBenzonitrilechemistryExcited stateSubstituentGeneral Physics and AstronomyPhysical and Theoretical ChemistryPhotochemistryMedicinal chemistryExcited singletPhysical Chemistry Chemical Physics
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Intramolecular charge transfer and dual fluorescence of 4-(dimethylamino)benzonitrile: ultrafast branching followed by a two-fold decay mechanism.

2011

International audience; In this contribution we present new experimental and theoretical results for the intramolecular charge transfer (ICT) reaction underlying the dual fluorescence of 4-(dimethylamino) benzonitrile ( DMABN), which indicate that the fully twisted ICT (TICT) state is responsible for the time-resolved transient absorption spectrum while a distinct partially twisted ICT (pTICT) structure is suggested for the fluorescent ICT state.

Dual fluorescenceTime Factors010304 chemical physicsGeneral Physics and Astronomy010402 general chemistryBranching (polymer chemistry)Photochemistry01 natural sciencesFluorescenceFluorescence3. Good health0104 chemical sciences[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryBenzonitrilechemistry.chemical_compoundSpectrometry FluorescencechemistryIntramolecular forceparasitic diseases0103 physical sciencesUltrafast laser spectroscopyNitrilesQuantum TheoryPhysical and Theoretical ChemistryUltrashort pulsePhysical chemistry chemical physics : PCCP
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The intraoral device of overlaid disk-holding splints as a new in situ oral biofilm model

2014

Objectives: To design a device that allows the formation of in situ oral biofilm with similar characteristics to those from the dental plaque, overcoming the limitations of previous devices. Study Design: The Intraoral Device of Overlaid Disk-holding Splints (IDODS) was designed and manufactured. To test its validity, five healthy adult volunteers wore them for two and four days allowing the biofilm to grow without any type of distortion. After each period, the thickness, vitality and structure of the formed biofilm were measured with a Confocal Laser Scanning Microscope (CLSM) in combination with a dual fluorescence solution. All volunteers filled out a Likert-type questionnaire to evaluat…

In situDual fluorescencebusiness.industryResearchBiofilmDentistryOdontologíaDental plaquemedicine.diseaseOral cavity:CIENCIAS MÉDICAS [UNESCO]Oral hygieneCiencias de la saludCommunity and Preventive DentistrySplintsIntraoral deviceUNESCO::CIENCIAS MÉDICASmedicinebusinessGeneral Dentistry
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